Disipo Blog 5

[Blog 5] Why the reutilization of CO2 must be smart?

     We have seen that using CO2 for the production of e-fuels can be a solution to those industrial processes that require using a fuel (e.g., aviation, shipping and ironmaking). However, the use of CO2 for producing synthetic fuels is controversial. Some authors have recently called into question this concept, as CO2 is released to the atmosphere when the synthetic fuel is consumed, thus limiting the mitigation potential (CO2 is only re-used once, but not recycled continuously). Besides, the additional energy consumed to capture the CO2 (prior the methanation process) becomes meaningless in practice, since emissions are not avoided. Only in scenarios with a very high renewable energy penetration there may be a reduction in CO2 emissions when applying Power to Gas as carbon utilization within the industry sector.

     When CO2 originally comes from a fossil source, and the synthetic fuel is used in decentralized applications, there is a net carbon emission to the atmosphere. The only advantage of this overall scheme is that renewable electricity that would otherwise have been curtailed can be used. If biomass is used as primary energy input instead fossil fuels, then it is clear that CO2 emissions are neutral in the overall concept.

       If the synthetic fuel is used in the same or other centralized emitting source from which CO2 is captured (industry or power plant), then CO2 is really recycled. It acts, thanks to the hydrogen, as an “energy carrier” of the system. This is called multiple reuses or continuous recycling. Thus, the consideration of Power to Gas as a valid technology for CO2 utilization depends on the overall design and the end-use of the synthetic fuel. Several positive aspects can be highlighted in the latter case:

  • The use of primary fossil fuel is reduced close to zero, so there is an important CO2 emissions reduction (avoided emissions).
  • CO2 is constantly recirculated and it is not released to the atmosphere.
  • The whole system mainly works with renewable energy.

       This is the only concept with which it is possible to avoid CO2 emissions by using Power to Gas. It should be noted that under this configuration the synthetic fuel is not sold but used for self-consumption. The saving of purchasing fuel may lead to feasible business models.

Ongoing 60%

Project info

1 April 2021 – 30 June 2023

Total budget: 188,442.24 €

  Spain
  •  University of Zaragoza
   Japan
  •  Waseda University  (Nakagaki Lab)
  Austria
  •  K1-MET GmbH

General coordinator
M. Bailera (mbailera@unizar.es)
University of Zaragoza
Further information: cordis.europa.eu

[1] A review on CO2 mitigation in the Iron and Steel industry through Power to X processes. M Bailera, P Lisbona, B Peña, LM Romeo. Journal of CO2 Utilization, Volume 46, 1 April 2021, Pages 101456.
[2] CO2 recycling in the Iron and Steel Industry via Power-to-Gas and Oxy-Fuel Combustion. J Perpiñán, M Bailera, LM Romeo, B Peña, V Eveloy. Energies, Volume 14, 29 October 2021, Pages 7090.
[3] Revisiting the Rist diagram for predicting operating conditions in blast furnaces with multiple injections. M Bailera, T Nakagaki, R Kataoka. Open Research Europe, Volume 1:141, 29 November 2021.
[4] Synthetic natural gas production in a 1 kW reactor using Ni–Ce/Al2O3 and Ru–Ce/Al2O3: Kinetics, catalyst degradation and process design. M Bailera, P Lisbona, B Peña, A Alarcón, J Guilera, J Perpiñán, LM Romeo. Energy, Volume 256, 1 October 2022, Pages 124720.

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No 887077.

Ongoing 60%

Project info

1 April 2021 – 30 June 2023

Total budget: 188,442.24 €

  Spain
  •  University of Zaragoza
   Japan
  •  Waseda University  (Nakagaki Lab)
  Austria
  •  K1-MET GmbH

General coordinator
M. Bailera (mbailera@unizar.es)
University of Zaragoza
Further information: cordis.europa.eu

[1] A review on CO2 mitigation in the Iron and Steel industry through Power to X processes. M Bailera, P Lisbona, B Peña, LM Romeo. Journal of CO2 Utilization, Volume 46, 1 April 2021, Pages 101456.
[2] CO2 recycling in the Iron and Steel Industry via Power-to-Gas and Oxy-Fuel Combustion. J Perpiñán, M Bailera, LM Romeo, B Peña, V Eveloy. Energies, Volume 14, 29 October 2021, Pages 7090.
[3] Revisiting the Rist diagram for predicting operating conditions in blast furnaces with multiple injections. M Bailera, T Nakagaki, R Kataoka. Open Research Europe, Volume 1:141, 29 November 2021.
[4] Synthetic natural gas production in a 1 kW reactor using Ni–Ce/Al2O3 and Ru–Ce/Al2O3: Kinetics, catalyst degradation and process design. M Bailera, P Lisbona, B Peña, A Alarcón, J Guilera, J Perpiñán, LM Romeo. Energy, Volume 256, 1 October 2022, Pages 124720.

This project has received funding from the European Union’s Horizon 2020 research and innovation programme under the Marie Sklodowska-Curie grant agreement No 887077.